Butylbis(diphenylglyoximato)(pyridine-κN)cobalt(III)1
نویسندگان
چکیده
In the title compound, [Co(C(4)H(9))(C(14)H(11)N(2)O(2))(2)(C(5)H(5)N)], the Co(III) atom is coordinated by a butyl group, a nitro-gen-bonded pyridine and two N,N'-bidentate diphenyl-glyoximate ligands in a distorted octa-hedral geometry. The crystal structure features two short O-H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å.
منابع مشابه
Butylbis(dimethylglyoximato-κ2 N,N′)(pyridine-κN)cobalt(III)1
In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N'-bidentate dimethyl-glyoximate ligands in a distorted octa-hedral geometry. The bis-chelating dimethyl-glyoximate ligands, which occupy equatorial sites, are linked by strong intra-molecular O-H⋯O ...
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The title compound, [Co(C(14)H(14)Cl)(C(4)H(6)N(2)O(2))(2)(C(5)H(5)N)], is a model compound for the more complex cobalamines like vitamins B(12). The Co(III) atom is coordinated by a (4'-chloro-methyl-[1,1'-biphen-yl]-4-yl)methyl group, an N-bonded pyridine and two N,N'-bidentate dimethyl-glyoximate ligands in a distorted octa-hedral geometry. The glyoximate ligands exhibit intra-molecular O-H⋯...
متن کامل[N′-(3-Methoxy-2-oxidobenzylidene-κO 2)benzohydrazidato-κ2 N′,O]tris(pyridine-κN)cobalt(III) perchlorate
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012